Formation of intermediate gas-liquid system in aromatics’ thin layers
نویسندگان
چکیده
The present work discusses IR spectroscopic experiments and quantum- chemical DFT study of structure intermolecular binding in the intermediate gas?liquid systems aromatics, namely, benzene, furane, pyridine thiophene. These can be generated thin layers near a solid surface by two different methods, depending on physical properties sample. first method includes evaporation with subsequent compression sample an optical cell variable thickness, it is applied to volatile components: For benzene second used, which involves heating-initiated into closed inter-window space after-cooling It was shown that formed layer not adsorbate or condensate. data obtained these methods lead conclusion given considered aromatics manifest dual spectral change each other varying external conditions. According calculation results, spatial arrangement aromatic described as combination ?- ?-bonded clusters, simulate gas liquid phase state properties.
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ژورنال
عنوان ژورنال: Journal of The Serbian Chemical Society
سال: 2023
ISSN: ['1820-7421', '0352-5139']
DOI: https://doi.org/10.2298/jsc211003087k